(R)-RUCL[(P-CYMENE)(DM-BINAP)]CL

(R)-RUCL[(P-CYMENE)(DM-BINAP)]CL - Names and Identifiers

Name	(R)-RuCl[(p-cymene)(DM-BINAP)]Cl Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl
Synonyms	BINAP)]Cl (p-cymene)((R)-xyL [RuCl(p-cymene)((R)-xylbinap)]Cl (R)-RUCL[(P-CYMENE)(DM-BINAP)]CL -binaphthyl}(p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((R)-xylbinap)]C CHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}(P-CYMENE)RUTHENIUM(II) CHLORIDE,[RUCL(P-CYMENE)((R)-XYLBINAP)]C Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl (R)-RuCl[(p-cymene)(DM-BINAP)]Cl Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl
CAS	944451-24-5

(R)-RUCL[(P-CYMENE)(DM-BINAP)]CL - Physico-chemical Properties

Molecular Formula	C62H60Cl2P2Ru
Molar Mass	1039.08
Melting Point	>100°C
Appearance	Powder
Color	orange to brown
Storage Condition	2-8°C
Sensitive	air sensitive

(R)-RUCL[(P-CYMENE)(DM-BINAP)]CL - Risk and Safety

WGK Germany

(R)-RUCL[(P-CYMENE)(DM-BINAP)]CL - Introduction

(R)-RuCl[(p-cymene)(DM-BINAP)]Cl Chloro{(R)-( )-2,2 '-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl, also known as (R)-RuCl[(p-cymene)(DM-BINAP)]Cl or rhodium (II) chloride [RuCl(p-cymene)((R)-xylbinap)]Cl, is an organometallic compound. The following is a description of the properties, uses, preparation and safety information of the compound:

Nature:
-Appearance: It is a solid with brownish red to reddish brown crystals.
-Solubility: Soluble in common organic solvents (such as dimethylformamide, dichloromethane), insoluble in water.
-Melting point: about 120-125 degrees Celsius.
-Stability: It is stable in an inert gas environment, but may be decomposed by the influence of moisture and oxygen in the air.

Use:
-As a catalyst: Because it contains ruthenium and phosphine ligands, it is often used as a catalyst, especially in asymmetric synthesis reactions, such as catalytic asymmetric hydrogenation, asymmetric cycloaddition, etc.

Preparation Method:
-The compound can be prepared by the method of synthetic metal organic chemistry. Typically, the chloride intermediate is formed by reaction in the presence of RuCl(p-cymene)Cl2 and (R)-( )-2,2 '-bis (di-(3,5-xylenyl) phosphino)-1,1'-binaphthyl (DM-BINAP), which is then further processed to give the desired product.

Safety Information:
-This is an organometallic compound that is potentially dangerous and toxic. During operation or use, it is necessary to follow appropriate safety procedures, including wearing appropriate protective equipment (such as gloves, glasses and laboratory coats).
-It should be operated in a well-ventilated area to avoid inhalation of vapor or dust.
-The contact and usage of this compound should be strictly controlled to avoid skin contact and inhalation.
-Waste Disposal: Waste shall be disposed of or recycled safely in accordance with local laws and regulations.

Last Update：2024-04-09 21:04:16